The title compound, C 20 H 26 N 4 , was prepared by a condensation reaction between p-dimethylaminobenzaldehyde and ethylenediamine. The molecule contains a crystallographically imposed twofold axis of symmetry.
N,N′-Bis(aminopropyl)-1,4-benzylidenediammonium diperchlorate
✍ Scribed by Yang, Shi-Ping ;Chen, Hong-Mei ;Znang, Fan ;Yu, Xi-Bin ;Weng, Lin-Hong
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 340 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The structure determination of the title compound, [C 14 H 24 N 4 ](ClO 4 ) 2 , indicates that intermolecular hydrogen bonds between the N atom of the aminopropyl group and an O atom of the perchlorate result in a two-dimensional layer structure. The cation has crystallographic inversion symmetry.
📜 SIMILAR VOLUMES
The title compound, [Cu 2 (C 15 H 13 ClP) 4 (C 30 H 28 N 2 )](ClO 4 ) 2 , was synthesized by the reaction of 9,10-bis[(n-propylamino)methyl]anthracene and 6-chloro-2-(diphenylphosphino)pyridine with [Cu(CH 3 CN) 4 ]ClO 4 . The Cu atoms adopt a trigonal±planar geometry and the cation is centrosymmetr
In the crystal structure of the title compound, C 14 H 17 -N 3 O 2 2+ Á2ClO 4 À , at 180 K, OÐHÁ Á ÁO hydrogen-bonded dimers are formed across inversion centres.