The 54.2 MHz I7O NMR spectra of a series of naturally occurring coumarins and furocoumarins and those of a number of related model compounds are described. The ''0 chemical shifts of the furocoumarins can be predicted by the evaluation of the data of substructures in model compounds. syn-Periplanar
NMR study of some coumarins and furocoumarins methylated
β Scribed by R. Miranda; L. Santana; E. Uriarte; G. Zagotto
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 260 KB
- Volume
- 50
- Category
- Article
- ISSN
- 1386-1425
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β¦ Synopsis
The 1H and 13C NMR spectra of various methylcoumarins and methylfuroeoumarins are reported. All signals were assigned and the influence on chemical shifts of methylation at various positions was determined.
π SIMILAR VOLUMES
## Abstract The signal shifts caused by replacing the carbonyl oxygen by sulphur represent a valuable method of assignment of the ^13^C NMR signals in coumarins and furocoumarins substituted at the benzoic and furanoic rings.
Carbon-1 3 spectral assignments of five pyrano[3,2-c] [l]benzopyran-5(2H) -ones, five pyrano[2,3-c] [l ]benzopyran-5(2H)ones and five 2-methylfuro[2,3-c] [ l ] benzopyran-4-ones and of 2-methylfuro[3, 2-c] [l]benzopyran-4-one and 4-(2-chloroallyl)-3-hydroxycoumarin were made from mutual correlations
13C NMR data for several simple coumarins are reported. The ysvn effect of a 5-methoxy substituent on the C-4 chemical shift was observed and measured. The effects of an 8-iodo substituent on the chemical shifts of the carbons of the coumarinic skeleton are discussed.