## Abstract The diterpene trachylobane and a series of derivatives have been completely analysed by FT ^13^C NMR spectroscopy. All ^13^C frequencies for trachylobanol have been unambiguously assigned by experimental techniques, i.e. by proton singleβfrequency selective decoupling and shift reagent
A novel assignment method in the 13C NMR spectroscopy of coumarins and furocoumarins
β Scribed by Helmut Duddeck; M. Hanni A. Elgamal; Faten K. Abd Elhady; Nagwa M. M. Shalaby
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 117 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0749-1581
No coin nor oath required. For personal study only.
β¦ Synopsis
Abstract
The signal shifts caused by replacing the carbonyl oxygen by sulphur represent a valuable method of assignment of the ^13^C NMR signals in coumarins and furocoumarins substituted at the benzoic and furanoic rings.
π SIMILAR VOLUMES
## Abstract The initial assignments for Cβ6 and Cβ8 in the carbon spectrum of estrone [3βhydroxyestraβ1,3,5(10)βtrieneβ17βone] were reversed by a subsequent group of investigators. Recent respected reference publications have reproduced these conflicting sets of data, reflecting an uncertainty rega
The 'H and 13C NMR spectra of a sulphamoyl derivative of DL-camphor have been examined. The unequivocal assignment of the position of substitution has been achieved by the attached proton test, 2D correlation spectroscopy and NOE difference spectroscopy.