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A question of assignments in the 13C NMR of estrone and related structures

✍ Scribed by William B. Smith

Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
191 KB
Volume
28
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The initial assignments for C‐6 and C‐8 in the carbon spectrum of estrone [3‐hydroxyestra‐1,3,5(10)‐triene‐17‐one] were reversed by a subsequent group of investigators. Recent respected reference publications have reproduced these conflicting sets of data, reflecting an uncertainty regarding the correct assignments. The implied question has been answered with the aid of APT, 2D COSY and HETCOR experiments.

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