We report on the wealth of IR spectra of single crystals of the C,, complex with chloro(tripheny1phosphine)gold grown from toluene solution. The spectra are strongly temperature-dependent at about 200 K. The dependence of the spectral parameters is attributed to variations in the molecular dynamics
โฆ LIBER โฆ
NMR study of molecular dynamics in C602([(C6H5)3P] AuCl) crystal
โ Scribed by L. Firlej; B. Kuchta; Sz. Roszak
- Book ID
- 117540832
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 454 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0379-6779
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## Abstract The ^13^C and ^31^P NMR spectra of the triply ^13^C labelled tribenzoylphosphine [] oriented in a nematic phase have been recorded. From the spectral analysis one obtains the average CPC valence bond angle value (95.9ยฐยฑ 0.2), and the phosphorus chemical shift anisotropy ฮฯ(ฯ~โฅ๏ธ~ โ ฯ ~โฅ~