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Infrared spectra of the new molecular complex C60 ·2[(C6H5)3P]AuCl·0.1 C6H5CH3

✍ Scribed by S. Król; A. Łapiński; A. Graja

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
426 KB
Volume
6
Category
Article
ISSN
1616-301X

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✦ Synopsis

We report on the wealth of IR spectra of single crystals of the C,, complex with chloro(tripheny1phosphine)gold grown from toluene solution. The spectra are strongly temperature-dependent at about 200 K. The dependence of the spectral parameters is attributed to variations in the molecular dynamics of the C, molecules and changes in the interactions between the f ullerene and donorlsolvent molecules. Some general considerations on the origin of the IR spectral variation vs. temperature are also presented.

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