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31P and 13C NMR study of tribenzolyphosphine (CC6H5)3 Oriented in a Liquid Crystal

✍ Scribed by A. Cogne; L. Wiesenfeld; J. B. Robert; R. Tyka

Publisher: John Wiley and Sons
Year: 1980
Tongue: English
Weight: 337 KB
Volume: 13
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270130115

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✦ Synopsis

Abstract

The ^13^C and ^31^P NMR spectra of the triply ^13^C labelled tribenzoylphosphine [] oriented in a nematic phase have been recorded. From the spectral analysis one obtains the average CPC valence bond angle value (95.9°± 0.2), and the phosphorus chemical shift anisotropy Δσ(σ~∥︁~ – σ ~⊥~) which is equal to 75 ± 15 ppm.

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