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NMR studies of the conformational behaviour and tautomerism of bis- and tris-saccharidoguanidines

✍ Scribed by Gábor Tóth; Tamás Gáti; István Pintér; József Kovács; Rainer Haessner

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
139 KB
Volume
39
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The reaction of an acetyl‐protected symmetrical sugar carbodiimide with amines yielded the corresponding trisubstituted guanidine derivatives 2–6 with two or three sugar units. Their tautomerism, isomerism and conformational behaviour were elucidated by application of one‐ and two‐dimensional ^1^H and ^13^C NMR spectroscopy. The rate of tautomerisation was calculated from ROESY exchange measurements. Copyright © 2001 John Wiley & Sons, Ltd.

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