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1H and 13C NMR studies of asymmetrically substituted bis- and tris-Tröger's bases

✍ Scribed by J. Elguero; A. Fruchier; T. Mas; C. Pardo

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
101 KB
Volume
43
Category
Article
ISSN
0749-1581

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✦ Synopsis

The (1)H and (13)C NMR spectra of two stereoisomeric bis-Tröger's bases and four stereoisomeric tris-Tröger's bases asymmetrically substituted on the external aromatic rings were recorded and the corresponding signals assigned. The relative configuration of the stereogenic units has been unequivocally determined on the basis of homoallylic couplings and NOE experiments.

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