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Structure and Conformational Exchange of PtCl2[Bis(undecenylseleno)ferrocene] Studied by NMR Spectroscopy

✍ Scribed by Xi-An Mao; Jun-Zhi Yao; Bing-Shou Tian; Yuan-Yin Chen

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
483 KB
Volume
34
Category
Article
ISSN
0749-1581

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✦ Synopsis

One-and two-dimensional NMR techniques were applied to the study of the structure and the intramolecular exchange dynamics of the newly synthesized complex cis-PtCI, 1 ,l'-bis(undeceny1seleno)ferrocenel in CDCl, solution. COSY, HMQC and NOESY experiments were performed. Unambiguous assignments for the cyclopentadienyl ring protons were achieved and the dl-meso exchange rate constants were determined.

KEY WORDS platinum(I1) complex; intramolecular dl-meso exchange; rate constants

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