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NMR studies of complex formation between N-methyl morpholine and sulphur dioxide

✍ Scribed by R. K. Harris; R. A. Spragg

Publisher
John Wiley and Sons
Year
1969
Tongue
English
Weight
334 KB
Volume
1
Category
Article
ISSN
0749-1581

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✦ Synopsis

Proton magnetic resonance spectra of methylene dichloride solutions containing N-methyl morpholine and sulphur dioxide have been studied as a function of temperature. Complex formation reduces the rate of interchange of magnetic sites via inversion at nitrogen but increases the rate of ring inversion. The conformational preference of the complex is discussed. It is suggested that interaction with SO, may be a useful general method of studying nitrogen inversion.

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