We report on the synthesis and characterization of two silicon clathrates, Na 8 Si 46 and Na x Si 136 (x ؍ 4+23), by powder X-ray di4raction, combined with Rietveld pro5le analysis. In Na 8 Si 46 , no deviation from the ideal stoichiometry is observed. In Na x Si 136 , systematic changes in X-ray
✦ LIBER ✦
NMR and X-ray Spectroscopy of Sodium−Silicon Clathrates †
✍ Scribed by He, Jiliang; Klug, Dennis D.; Uehara, Kentaro; Preston, Keith F.; Ratcliffe, Christopher I.; Tse, John S.
- Book ID
- 127170334
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 132 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0022-3654
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