Synthesis and characterization of a [5.5]paracyclophane-containing silicon by NMR spectroscopy and X-ray crystallography

✍ Scribed by Elizabeth Gómez; Norberto Farfán

• Publisher: John Wiley and Sons
• Year: 1999
• Tongue: English
• Weight: 179 KB
• Volume: 10
• Category: Article
• ISSN: 1042-7163
• DOI: 10.1002/(sici)1098-1071(1999)10:5<351::aid-hc2>3.0.co;2-i

✦ Synopsis

The synthesis and characterization of 1,3,10,12-tetraoxo-2,11-(diphenylsilylene)[5.5]paracyclophane obtained by reaction of 1,4-benzenedimethanol and dichlorodiphenylsilane is reported. The structure was established by mass spectrometry; 1 H, 13 C, and 29 Si NMR; and X-ray diffraction analysis.