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NMR and optical activity observations on the helix–coil transition in poly(γ-benzyl L-glutamate) solutions

✍ Scribed by Kang-Jen Liu; J. S. Lignowski; Robert Ullman

Publisher
Wiley (John Wiley & Sons)
Year
1967
Tongue
English
Weight
338 KB
Volume
5
Category
Article
ISSN
0006-3525

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✦ Synopsis

The helix-coil transition of poly(ybenzy1 L-glutamate) was studied by comparing proton magnetic relaxation behavior with optical activity studies. The transition temperatnre as determined by magnetic relaxation was lower than that obtained by optical activity.

The relationship of these experiments with previous NMR studies and also with calorimetric investigation of the trsnsition is developed.

The concentration dependence of the transition was also studied.

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