Nitroxide radicals in studies of the fine bonded layer structure of modified silicas
✍ Scribed by Pavel G. Mingalyov; Alexander Yu. Fadeev; Sergei M. Staroverov; Georgii V. Lisichkin; Elena V. Lunina
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 860 KB
- Volume
- 646
- Category
- Article
- ISSN
- 1873-3778
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## Abstract Various __N__‐nitrosamines were photolyzed in toluene solution in the temperature range −100°C to −30°C to yield dialkyl nitroxides. The nitrosamines studied were __N__‐nitrosodimethylamine, __N__‐nitrosodiethylamine, __N__‐nitrosodipropylamine, __N__‐nitrosodibutylamine and __N__‐nitro
SCF molecular orbital calculations using INDO method have been performed for dimethyl nitroxide (DMNO)-methanol and DMNO-acetylene hydrogen bond systems. Negative spin densiw on the hydroql proton of methanol which has been confirmed by our previous NBIR studies was reproduced only for the model whe