## Abstract The ^13^C and ^15^N NMR spectra of some __ortho‐, meta‐__ and __para__‐substituted methanesulphonanilides were recorded. Correlations of the ^13^C chemical shifts with the appropriate substituent chemical shifts (SCS) for monosubstituted benzenes were excellent and showed enhancement of
Nitrogen and carbon NMR of some benzofuroxans
✍ Scribed by M. Witanowski; L. Stefaniak; S. Biernat; G. A. Webb
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 295 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
^15^N and ^14^N NMR spectra show that there is no valence tautomerism involving the nitro group in nitro derivatives of benzofuroxan systems and that the N‐oxide function has a fixed position in the furoxan ring. Carbon chemical shifts of molecules with one, two or three furoxan rings attached to a benzene ring reveal additivity of effects which makes possible a complete and unambiguous assignment of the shifts.
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## Abstract The ^1^H, ^13^C, and ^15^N shifts of 10 nitrogen‐containing bi‐ and triaryls are reported, including the coupling constants of the fluoro substituents with all nuclei. The proton and carbon resonances of the hetaryl structures are completely assigned. Copyright © 2001 John Wiley & Sons,
## Abstract The PFT ^13^C NMR spectra of some representative 1‐azirines are discussed. Two striking features are the large ^13^C^1^H spin coupling constants and the diagnostic chemical shift of C~3~.
The free acids and sodium salts of a series of sulphonated azobenzene dyestu †s were examined in the solid and solution states by 13C and 15N NMR spectroscopy. In solution the spectra of both the free acids and salts are characteristic of trans-azobenzene structures, as are the spectra of the solid
N chemical shifts are reported for 10 mesoionic oxadiazoles and thiadiazoles. Some supporting 14 N and 13 C NMR data are also reported, together with some ab initio molecular orbital calculations and x-ray diffraction data. The relation between compound structure and 15 N chemical shifts is discusse
## Abstract The ^13^C n.m.r. spectrum of benzofuroxan at −15°C is assigned on the basis of selective decoupling experiments and by comparison with the ^13^C chemical shifts of model compounds. The ^13^C spectra were also measured in trifluoroacetic acid as a solvent. From the temperature dependence