Carbon-I3 chemical shifts of 26 arninoalkynyl derivatives of 1,3,4-thiadiazol-2(3H)-one and 1,3,4-thiadiazolin-2-ylidenebenzarnide have been determined.
Carbon-13 NMR of some representative reactive small ring nitrogen heterocycles
✍ Scribed by V. Nair
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 146 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The PFT ^13^C NMR spectra of some representative 1‐azirines are discussed. Two striking features are the large ^13^C^1^H spin coupling constants and the diagnostic chemical shift of C~3~.
📜 SIMILAR VOLUMES
The free acids and sodium salts of a series of sulphonated azobenzene dyestu †s were examined in the solid and solution states by 13C and 15N NMR spectroscopy. In solution the spectra of both the free acids and salts are characteristic of trans-azobenzene structures, as are the spectra of the solid
15N, 1 7 0 and 33S N M R chemical shifts were determined for some aliphatic and aromatic sulphonamides, sulphinamides, sulphenamides and related sulphones and sulphoxides. The 1 7 0 and NMR chemical shifts change only slightly for the sulphonyl compounds. In the sulphinyl componnds, on the other han
## Abstract Carbon‐13 NMR spectra of the σ‐adduct complexes formed in liquid ammonia between the amide ion and some 2‐R‐pyrimidines, some 4‐chloro‐2‐R‐pyrimidines (R = dimethylamino‐, __N__‐methylanilino, piperidino‐, morpholino‐, phenyl‐), 5‐bromo‐2‐piperidinopyrimidine and pyrimidine itself are d