(Nitrito-O,O')bis(triphenylphosphine)copper(I), (PPh3)2Cu(NO2-O,O')
✍ Scribed by Halfen, J. A. ;Tolman, W. B.
- Book ID
- 114511508
- Publisher
- International Union of Crystallography
- Year
- 1995
- Tongue
- English
- Weight
- 318 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.046 wR factor = 0.101 Data-to-parameter ratio = 15.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, [Cu(C~8~H~6~NO~2~)~2~(C~6~H~7~NO)~2~(H~2~O)], the Cu^2+^ ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment, and is bonded to three carboxylate O atoms of two 3-pyridylacrylate anions (monodentate and asymetric bidentate), two pyridine N atoms of