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Nickel(II)—bleomycin: spectral investigation of the metal binding site

✍ Scribed by Andrea Dei; Dante Gatteschi


Book ID
108403564
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
459 KB
Volume
17
Category
Article
ISSN
0162-0134

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Model compounds for the metal binding site of bleomycin with a CH2CONH group (PYML-3) or a tert-butyl group (PYML-4) as stegic environmental factors are synthesized. These exhibit metal binding properties similar to those of bleomycin. In particular, PYML-4 shows oxygen activation up to 71 % of th