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Ni-catalyzed asymmetric reductive allylation of aldehydes with allylic carbonates

โœ Scribed by Tan, Zhuozhen; Wan, Xiaolong; Zang, Zhenhua; Qian, Qun; Deng, Wei; Gong, Hegui

Book ID
121511359
Publisher
Royal Society of Chemistry
Year
2014
Tongue
English
Weight
675 KB
Volume
50
Category
Article
ISSN
1359-7345

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Ni-Catalyzed Reductive Allylation of Una
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โœ Yijing Dai; Fan Wu; Zhenhua Zang; Hengzhi You; Prof.โ€…Dr. Hegui Gong ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 290 KB ๐Ÿ‘ 1 views

Game of two electrophiles: Two partially positively charged sp(3) carbon atoms can be connected by using a catalytic Ni species in the presence of an environmentally benign Zn reductant, delivering allylated alkanes. This unprecedented approach allowed a variety of unactivated alkyl halides and subs