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Ni-Catalyzed Reductive Allylation of Unactivated Alkyl Halides with Allylic Carbonates

✍ Scribed by Yijing Dai; Fan Wu; Zhenhua Zang; Hengzhi You; Prof. Dr. Hegui Gong

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 290 KB
Volume: 18
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.201102984

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✦ Synopsis

Game of two electrophiles: Two partially positively charged sp(3) carbon atoms can be connected by using a catalytic Ni species in the presence of an environmentally benign Zn reductant, delivering allylated alkanes. This unprecedented approach allowed a variety of unactivated alkyl halides and substituted allylic carbonates to regioselectively afford E-alkenes in good to excellent yields.

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