Cobalt-Catalyzed Reductive Allylation of Alkyl Halides with Allylic Acetates or Carbonates
β Scribed by Xin Qian; Dr. Audrey Auffrant; Abdellah Felouat; Dr. Corinne Gosmini
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 341 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
Game of two electrophiles: Two partially positively charged sp(3) carbon atoms can be connected by using a catalytic Ni species in the presence of an environmentally benign Zn reductant, delivering allylated alkanes. This unprecedented approach allowed a variety of unactivated alkyl halides and subs
Nickel-and palladium-catalyzed cross-coupling reactions of organic halides with organometallic reagents is one of the most versatile carbonΒ±carbon bond-forming reactions in organic synthesis. [1] In most cases, aryl and vinyl halides are employed as organic halides, yielding sp 2 Β±sp, sp 2 Β±sp 2 , a
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