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New types of carbonylation with insertion of acetylene

✍ Scribed by L. Cassar; G.P. Chiusoli


Publisher
Elsevier Science
Year
1965
Tongue
French
Weight
148 KB
Volume
6
Category
Article
ISSN
0040-4039

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✦ Synopsis


We recently reported (1) on the reactions of substitp ted acetylenes with allylic halides and nickel carbonyl in acetone-water at room tenperoture and atmospheric pressure.

Unsaturated ketones and lactones derived fror! cyclopentenones and cyclchexenones were obtained.


πŸ“œ SIMILAR VOLUMES


Chemistry of acetylenic ethers XXXIX: Re
✍ H. Vieregge; J. F. Arens πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 393 KB

## Abstract Acetylenic ethers V react with aldehydes in aqueous medium at room temperature to yield the hydroxy esters VII and IX, often together with a small amount of the unsaturated ester VIII. The acetylenic ethers do not react in such a way with ketones and aromatic aldehydes but a similar rea