Insertion Reactions of [ReH(CO)5–n(PMe3)
✍
Daniel Nietlispach; Dario Veghini; Heinz Berke
📂
Article
📅
1994
🏛
John Wiley and Sons
🌐
German
⚖ 853 KB
## Me3P Me3P PMe, 1 2 3 stereoisomers which display hydride/PMe, cis-and hydride/CO trans-configurations. The syntheses of 2 and 3 were recently reported [5], and 1 was obtained in high yield by reduction of [ReCl(CO),(PMe,),] with Na in THF and subsequent acidification with H,O. Out of the seri