✦ LIBER ✦

Chemistry of acetylenic ethers XXXIX: Reactions of acetylenic ethers with carbonyl compounds in aqueous solution

✍ Scribed by H. Vieregge; J. F. Arens

Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 393 KB
Volume: 78
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19590781113

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✦ Synopsis

Abstract

Acetylenic ethers V react with aldehydes in aqueous medium at room temperature to yield the hydroxy esters VII and IX, often together with a small amount of the unsaturated ester VIII. The acetylenic ethers do not react in such a way with ketones and aromatic aldehydes but a similar reaction occurs with ethyl mesoxalate.

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