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New triply hydroxo-bridged complexes of chromium(III), cobalt(III), and rhodium(III): crystal structure of tris(.mu.-hydroxo)bis[(1,4,7-trimethyl-1,4,7-triazacyclononane)chromium(III)] triiodide trihydrate

✍ Scribed by Wieghardt, Karl.; Chaudhuri, Phalguni.; Nuber, Bernhard.; Weiss, Johannes.


Book ID
121279858
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
666 KB
Volume
21
Category
Article
ISSN
0020-1669

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HigIl-resolution absorption, iuminesccnce, Zeeman and MCD experiments were performed cm sir& crystals of the title compound. The singlet-tripiet and trip&t-quintet exchange splittings in the ground state are 138 and 267 cm-'. respectively. The corresponding exchange parameters are 2J= -128 cm-' andj

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