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ChemInform Abstract: Ruthenium-Mediated Amidation of Saturated C—H Bonds and Crystal Structure of a Bis(tosyl)amidoruthenium(III) Complex of 1,4,7-Trimethyl-1,4,7-triazacyclononane.

✍ Scribed by Sze-Man Au; Suo-Bo Zhang; Wai-Hong Fung; Wing-Yiu Yu; Chi-Ming Che; Kung-Kai Cheung

Book ID
101875912
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

1999 sulfonamides sulfonamides (hydrazides, ureides) (benzene compounds) Q 0560

15 -113

Ruthenium-Mediated Amidation of Saturated C-H Bonds and Crystal Structure of a Bis(tosyl)amidoruthenium(III) Complex of 1,4,7-Trimethyl-1,4,7-triazacyclononane.

-Title compound (II) is prepared and its structure is determined by X-ray analysis. This complex (II) is used as reagent and as catalyst for the amidation of saturated C-H bonds of reactants, e.g. (I), giving sulfur amides (III). An electrophilic tosylimidoruthenium intermediate is implicated based on Hammett correlation studies and trapping experiments. -(AU, SZE-MAN; ZHANG, SUO-BO; FUNG,

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