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Exchange coupling in tris(.mu.-hydroxo)bis[(1,4,7-trimethyl-1,4,7-triazacyclononane)chromium(III)] triperchlorate trihydrate

✍ Scribed by Bolster, D. Eric; Guetlich, Philipp; Hatfield, William E.; Kremer, S.; Mueller, E. Wolfgang; Wieghardt, Karl


Book ID
126988152
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
671 KB
Volume
22
Category
Article
ISSN
0020-1669

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πŸ“œ SIMILAR VOLUMES


Exchange interactions in a trigonal chro
✍ Hans Riesen; Hans U. GΓΌdel; Phalguni Chaudhuri; Karl Wieghardt πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 315 KB

HigIl-resolution absorption, iuminesccnce, Zeeman and MCD experiments were performed cm sir& crystals of the title compound. The singlet-tripiet and trip&t-quintet exchange splittings in the ground state are 138 and 267 cm-'. respectively. The corresponding exchange parameters are 2J= -128 cm-' andj