New thermosetting resin from terpenediphenol-based benzoxazine and epoxy resin

✍ Scribed by Hajime Kimura; Youhei Murata; Akihiro Matsumoto; Kiichi Hasegawa; Keiko Ohtsuka; Akinori Fukuda

• Publisher: John Wiley and Sons
• Year: 1999
• Tongue: English
• Weight: 190 KB
• Volume: 74
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/(sici)1097-4628(19991128)74:9<2266::aid-app16>3.0.co;2-5

✦ Synopsis

Terpenediphenol-based benzoxazine was prepared from terpenediphenol, formaline, and aniline. Curing behavior of the benzoxazine with epoxy resin and the properties of the cured resin were investigated. Consequently, the curing reaction did not proceed at low temperatures, but it proceeded rapidly at higher temperatures without a curing accelerator. The properties of the cured resin both from neat resins and from reinforced resins with fused silica were evaluated, respectively. The cured resins showed good heat resistance, mechanical properties, electrical insulation, and especially water resistance, compared with the cured resin from bisphenol A type novolac and epoxy resin.