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New Synthesis of benzocyclobutene

โœ Scribed by Sanders, Andrea; Giering, Warren P.


Book ID
127171356
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
176 KB
Volume
38
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


Convenient synthesis of benzocyclobutene
โœ Markgraf, J. Hodge.; Basta, Salvatore J.; Wege, Peter M. ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 452 KB
Synthesis of scillascillin, a naturally
โœ Viresh H. Rawal; Michael P. Cava ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 185 KB

The novel homoisoflavanone scillascillin has been synthesized from phloroglucinol. The sequence described represents the first synthesis of a naturally occuring benzocyclobutene. The first example of a silyl transfer involving an 8-membered transition state is reported.

Functionalized aryllithium intermediates
โœ Peter D. Brewer; Jayaram Tagat; Charles A. Hergrueter; Paul Helquist ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 128 KB

Benzocyclobutenes' have been found to be quite useful species for the synthesis of several types of compounds, including members of the alkaloid,\* steroid,3 and polycyclic ter-penoid4 classes of natural products. The key step in each of these syntheses may be rationalized in terms of a (2+4) cycloa