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New Regio- and Stereoselective Intermolecular Pauson—Khand Reactions of Allenamides.

✍ Scribed by Loreto Anorbe; Amalia Poblador; Gema Dominguez; Javier Perez-Castells


Publisher
John Wiley and Sons
Year
2004
Weight
141 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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## Abstract Pauson–Khand reactions of functionalized allenes with different alkynes give cyclopentenones with generally high regio‐ and stereoselectivities. The allenes react through their external double bonds, giving cyclopentenones with exocyclic double bond at their β positions and predominantl