## Abstract The reaction proceeds strictly regioselectively: the fluorinated substituent is always found at the α‐position to the enone.
Stereoselectivity in the Intermolecular Pauson—Khand Reaction of Electron-Deficient Terminal Alkynes.
✍ Scribed by Jordi Sola; Antoni Riera; Miquel A. Pericas; Xavier Verdaguer; Miguel A. Maestro
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 24 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
1-Methyl-norbornene ester 9 and 1-methyl-2,3-diazabicyclo[2.2.1]heptene ester 10 were employed in intermolecular Pauson-Khand reactions with various terminal alkynes 11af to give the dimethyl 1-methyltricyclo[5.2.1.0 5,9 ]dec-7-en-6one 2,3-dicarboxylates 12 and 13, and diethyl 2,3-diaza-1methyltricy
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