The conversion of p-ethylanisole, via the tricarbonyl(diene)-iron complex (3), to the bicyclic amino ketone (2), which is a known precursor for aspidospermine total synthesis, is described. The synthetic route demonstrates the stability of the diene-Fe(C0)3 unit to a number of useful synthetic trans
β¦ LIBER β¦
New methodology for steroid total synthesis via organoiron complexes
β Scribed by Anthony J. Pearson; Geoffrey C. Heywood
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 202 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The application of tricarbonyl(4-methoxy-l-methylcyclohexadienyl)
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