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New approach to aspidospermine total synthesis using organoiron complexes

✍ Scribed by Anthony J. Pearson

Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 193 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)82057-8

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✦ Synopsis

The conversion of p-ethylanisole, via the tricarbonyl(diene)-iron complex (3), to the bicyclic amino ketone (2), which is a known precursor for aspidospermine total synthesis, is described. The synthetic route demonstrates the stability of the diene-Fe(C0)3 unit to a number of useful synthetic transformations.

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