The conversion of p-ethylanisole, via the tricarbonyl(diene)-iron complex (3), to the bicyclic amino ketone (2), which is a known precursor for aspidospermine total synthesis, is described. The synthetic route demonstrates the stability of the diene-Fe(C0)3 unit to a number of useful synthetic trans
β¦ LIBER β¦
New approach to the synthesis of 6-ketosteroids via organoiron complexes.
β Scribed by Enrico Mincione; Anthony J. Pearson; Paolo Bovicelli; Malcolm Chandler; Geoffrey C. Heywood
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 159 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
New Methodology is descrrbed for the synthesis 6_ketosteroids, of potential value for the synthesis of 8-ecdysone, via tricarbonyl (4-methoxy-1-methylcyclohexadienyl)
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