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New method of forming the carbon-silicon bond. Reductive silylation of aromatic acids

✍ Scribed by Benkeser, Robert A.; Gaul, James M.

Book ID
126406138
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
137 KB
Volume
92
Category
Article
ISSN
0002-7863

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New method of preparing silyl substitute
New method of preparing silyl substituted carbanions by base catalyzed cleavage of carbon silicon bonds. Application to syntheses of olefins
✍ Hideki Sakurai; Ken-ichiro Nishiwaki; Mitsuo Kira πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 French βš– 187 KB

Silyl-substituted organometallic compounds of a general formula of R3SiC--R1R2M+ have been recognized to be effective intermediates in the conversion of carbonyl compounds and acid chlorides to olefins' and ketones,5 respectively.