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New method of preparing silyl substituted carbanions by base catalyzed cleavage of carbon silicon bonds. Application to syntheses of olefins

✍ Scribed by Hideki Sakurai; Ken-ichiro Nishiwaki; Mitsuo Kira


Book ID
104238479
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
187 KB
Volume
14
Category
Article
ISSN
0040-4039

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✦ Synopsis


Silyl-substituted organometallic compounds of a general formula of R3SiC--R1R2M+ have been recognized to be effective intermediates in the conversion of carbonyl compounds and acid chlorides to olefins' and ketones,5 respectively.