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ChemInform Abstract: Decarboxylative Carbon—Carbon Bond-Forming Transformations of (Hetero)aromatic Carboxylic Acids

✍ Scribed by Josep Cornella; Igor Larrosa


Book ID
112044111
Publisher
John Wiley and Sons
Year
2012
Weight
18 KB
Volume
43
Category
Article
ISSN
0931-7597

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Re 2 O 7 -Catalyzed Carbon-Carbon Bond Cleavage of Ketones into Carboxylic Acids with aq. TBHP. -Methyl and ethyl ketones are oxidized to the corresponding carboxylic acids in good yields using a catalytic amount of Re 2 O 7 and aq. tert.butyl hydroperoxide as oxidant. -