## Abstract The treatment of aromatic or aliphatic ketones with carbodiimides in the presence of a tri‐ or dinuclear manganese catalyst affords amides in good to excellent yields and quinoline derivatives as side products.
ChemInform Abstract: Re2O7-Catalyzed Carbon—Carbon Bond Cleavage of Ketones into Carboxylic Acids with aq. TBHP.
✍ Scribed by S. Gurunath; A. Sudalai
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Re 2 O 7 -Catalyzed Carbon-Carbon Bond Cleavage of Ketones into Carboxylic Acids with aq.
TBHP.
-Methyl and ethyl ketones are oxidized to the corresponding carboxylic acids in good yields using a catalytic amount of Re 2 O 7 and aq. tert.butyl hydroperoxide as oxidant. -
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