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ChemInform Abstract: Manganese-Catalyzed Cleavage of a Carbon—Carbon Single Bond Between Carbonyl Carbon and α-Carbon Atoms of Ketones.

✍ Scribed by Yoichiro Kuninobu; Tadamasa Uesugi; Atsushi Kawata; Kazuhiko Takai

Publisher
John Wiley and Sons
Year
2012
Weight
34 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The treatment of aromatic or aliphatic ketones with carbodiimides in the presence of a tri‐ or dinuclear manganese catalyst affords amides in good to excellent yields and quinoline derivatives as side products.

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