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New method for the synthesis of macrolides

✍ Scribed by Corey, E. J.; Kirst, Herbert A.

Book ID
127344693
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
261 KB
Volume
94
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

A New Method for the Construction of Mac
A New Method for the Construction of Macrolides Stereoselective Synthesis of (Β±)-Phoracantholide J. Preliminary communication
✍ Martin Petrzilka πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 German βš– 249 KB

## Abstract Starting from 5‐chloro‐2‐pentanone (**1**) the naturally occurring 10‐membered lactone phoracantholide J (**8a**) has been synthesized as its racemate in a sequence of six steps (__Scheme 2__). Salient features of the syntheis include an internal selenium assisted acetal formation (**4β†’

New synthetic method for orsellic acid t
New synthetic method for orsellic acid type macrolides by intramolecular alkylation of protected cyanohydrin. The synthesis of (Β±)-zearalenone.
✍ Takashi Takahashi; Hiroshi Ikeda; Jiro Tsuji πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 233 KB

## SummarE Zearalenone was synthesized by a general cyclization method of orsellic acid type macrolides having ketone moiety using the intramolecular alkylation of the protected cyanohydrin. This alkylation tolerates the presence of ester group and requires short reaction time.