✦ LIBER ✦

New synthetic method for orsellic acid type macrolides by intramolecular alkylation of protected cyanohydrin. The synthesis of (±)-zearalenone.

✍ Scribed by Takashi Takahashi; Hiroshi Ikeda; Jiro Tsuji

Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 233 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)90320-x

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✦ Synopsis

SummarE

Zearalenone was synthesized by a general cyclization method of orsellic acid type macrolides having ketone moiety using the intramolecular alkylation of the protected cyanohydrin. This alkylation tolerates the presence of ester group and requires short reaction time.

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