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A general synthetic method for 2,6-cyclodecadienone system by intramolecular alkylation of protected cyanohydrins

โœ Scribed by Takashi Takahashi; Hisao Nemoto; Jiro Tsuji

Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
243 KB
Volume
24
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

New synthetic method for orsellic acid t
New synthetic method for orsellic acid type macrolides by intramolecular alkylation of protected cyanohydrin. The synthesis of (ยฑ)-zearalenone.
โœ Takashi Takahashi; Hiroshi Ikeda; Jiro Tsuji ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 233 KB

## SummarE Zearalenone was synthesized by a general cyclization method of orsellic acid type macrolides having ketone moiety using the intramolecular alkylation of the protected cyanohydrin. This alkylation tolerates the presence of ester group and requires short reaction time.

Syntheses of new humulene derivatives; (
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โœ Takashi Takahashi; Kyoko Kitamura; Jiro Tsuji ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 261 KB

Hendrickson') reported a biogenetic hypothesis for bi-and tricyclic sesquiterpenes and suggested that cation \_l and cation ,2, derived from trans-and cis-farnesyl pyrophosphate respectively, were the most important key intermediates in the biosynthesis of sesquiterpenes. On the other hand, Parker 2