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New homochiral bis(oxazoline) ligands for asymmetric catalysis

✍ Scribed by O. Hoarau; H. Aït-Haddou; M. Castro; G.G.A. Balavoine

Book ID
118606576
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
629 KB
Volume
8
Category
Article
ISSN
0957-4166

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Simple phosphinite–oxazoline ligands for
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4-(Hydroxymethyl)oxazolines, derived from (S)-serine methyl ester and a variety of acid chlorides (RCOCl), were reacted with Ph 2 PCl to give new phosphinite-oxazoline P-N ligands. These mediate the palladium catalysed asymmetric alkylation with dimethyl malonate with the following racemic propenyl