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C2-Symmetric Chiral Bis(oxazoline) Ligands in Asymmetric Catalysis

✍ Scribed by Giovanni Desimoni; Giuseppe Faita; Karl Anker Joergensen


Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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C1-Symmetric Versus C2-Symmetric Ligands
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## Abstract A thorough experimental and theoretical study of the enantioselective cyclopropanation of alkenes catalyzed by chiral bis(oxazoline)– and azabis(oxazoline)–copper complexes, which comprise a new family of ligands that lack __C__~2~ symmetry, has been conducted. Surprisingly high enantio