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New families of ternary molybdenum (II) chlorides with octahedral Mo6 clusters

✍ Scribed by M. Potel; C. Perrin; A. Perrin; M. Sergent


Book ID
113187169
Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
314 KB
Volume
21
Category
Article
ISSN
0025-5408

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New superconducting ternary molybdenum c
✍ P. Gougeon; M. Potel; M. Sergent; P. Monceau πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science βš– 301 KB

The new ternary molybdenum chalcogenides of general formula M2, ' 2Mo6, X6n, 2 (M = Rb, Cs; X = S, Se) crystallize in the trigonal rhombohedral space group R3 (the same as for the Chevrel phases) and are characterized by the new condensed clusters Mo~2, Mo~8 , M024 and M030. Electrical resistivity m