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Synthesis and structure of a new octahedral molybdenum thiocyanide cluster complex K7[Mo6(μ3-S)8(CN)6]·8H2O

✍ Scribed by K. A. Brylev; A. V. Virovets; N. G. Naumov; Yu. V. Mironov; D. Fenske; V. E. Fedorov

Book ID: 110326521
Publisher: Springer
Year: 2001
Tongue: English
Weight: 341 KB
Volume: 50
Category: Article
ISSN: 1573-9171
DOI: 10.1023/a:1014021815570

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## Abstract New cluster compounds [H~3~O(Ph~3~PO)~3~]~2~[Mo~6~Cl~14~] (I) and [H(Ph~3~PO)~2~]~2~[Re~6~S~6~Br~8~] (II) have been prepared by the reaction of a acetonitrile solution of triphenylphosphane oxide Ph~3~PO with octahedral cluster complexes of molybdenum (H~3~O)~2~Mo~6~Cl~14~·6H~2~O and rh