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New Efficient Ruthenium Catalysts for Racemization of Alcohols at Room Temperature.

✍ Scribed by Gabor Csjernyik; Krisztian Bogar; Jan-E. Baeckvall

Publisher: John Wiley and Sons
Year: 2004
Weight: 19 KB
Volume: 35
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200449020

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Dynamic kinetic resolution (DKR) is an attractive method for the complete transformation of a racemic mixture into a single enantiomer. [1] The DKR of secondary alcohols is a prominent example, for which transition-metal-catalyzed racemization is coupled with enzymatic acylation. [2] In particular,