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Aminocyclopentadienyl Ruthenium Complexes as Racemization Catalysts for Dynamic Kinetic Resolution of Secondary Alcohols at Ambient Temperature.

✍ Scribed by Jun Ho Choi; Yoon Kyung Choi; Yu Hwan Kim; Eun Sil Park; Eun Jung Kim; Mahn-Joo Kim; Jaiwook Park

Publisher
John Wiley and Sons
Year
2004
Weight
343 KB
Volume
35
Category
Article
ISSN
0931-7597

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Aminocyclopentadienyl Ruthenium Chloride
Aminocyclopentadienyl Ruthenium Chloride: Catalytic Racemization and Dynamic Kinetic Resolution of Alcohols at Ambient Temperature
✍ Jun Ho Choi; Yu Hwan Kim; Se Hyun Nam; Seung Tae Shin; Mahn-Joo Kim; Jaiwook Par πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 102 KB

Dynamic kinetic resolution (DKR) is an attractive method for the complete transformation of a racemic mixture into a single enantiomer. [1] The DKR of secondary alcohols is a prominent example, for which transition-metal-catalyzed racemization is coupled with enzymatic acylation. [2] In particular,