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Aminocyclopentadienyl Ruthenium Chloride: Catalytic Racemization and Dynamic Kinetic Resolution of Alcohols at Ambient Temperature

โœ Scribed by Jun Ho Choi; Yu Hwan Kim; Se Hyun Nam; Seung Tae Shin; Mahn-Joo Kim; Jaiwook Park

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
101 KB
Volume
41
Category
Article
ISSN
0044-8249

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Aminocyclopentadienyl Ruthenium Chloride
Aminocyclopentadienyl Ruthenium Chloride: Catalytic Racemization and Dynamic Kinetic Resolution of Alcohols at Ambient Temperature
โœ Jun Ho Choi; Yu Hwan Kim; Se Hyun Nam; Seung Tae Shin; Mahn-Joo Kim; Jaiwook Par ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 102 KB

Dynamic kinetic resolution (DKR) is an attractive method for the complete transformation of a racemic mixture into a single enantiomer. [1] The DKR of secondary alcohols is a prominent example, for which transition-metal-catalyzed racemization is coupled with enzymatic acylation. [2] In particular,